SELECTIVE HYDROGENATION OF SIMPLE AND FUNCTIONALIZED CONJUGATED DIENES USING A BINUCLEAR PALLADIUM COMPLEX CATALYST PRECURSOR

Authors
CHO IS ALPER H
Citation
Is. Cho et H. Alper, SELECTIVE HYDROGENATION OF SIMPLE AND FUNCTIONALIZED CONJUGATED DIENES USING A BINUCLEAR PALLADIUM COMPLEX CATALYST PRECURSOR, Tetrahedron letters, 36(32), 1995, pp. 5673-5676
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
32
Year of publication
1995
Pages
5673 - 5676
Database
ISI
SICI code
0040-4039(1995)36:32<5673:SHOSAF>2.0.ZU;2-#
Abstract
The selective 1,2-hydrogenation of simple and functionalized conjugate d dienes is catalyzed by preactivation of the binuclear palladium comp lex, [(Bu(2)(t)PH)PdPBu(2)(t)](2), with oxygen, in THF at room tempera ture and I atm of hydrogen pressure, to form monoenes in excellent yie ld.