CHROMIUM-MEDIATED BENZYLIC OXIDATIONS BY SODIUM PERCARBONATE IN THE PRESENCE OF A PHASE-TRANSFER CATALYST

Authors
MUZART J AITMOHAND S
Citation
J. Muzart et S. Aitmohand, CHROMIUM-MEDIATED BENZYLIC OXIDATIONS BY SODIUM PERCARBONATE IN THE PRESENCE OF A PHASE-TRANSFER CATALYST, Tetrahedron letters, 36(32), 1995, pp. 5735-5736
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
32
Year of publication
1995
Pages
5735 - 5736
Database
ISI
SICI code
0040-4039(1995)36:32<5735:CBOBSP>2.0.ZU;2-8
Abstract
In the presence of catalytic amounts of (n-Bu(3)Sn0)(2)CrO2, Adogen 46 4 and p-toluenesulfonic acid, benzylic methylene groups are effectivel y oxidized into alcohols and ketones by sodium percarbonate in refluxi ng acetonitrile.