NEW ALLYL GROUP ACCEPTERS FOR PALLADIUM-CATALYZED REMOVAL OF ALLYLIC PROTECTIONS AND TRANSACYLATION OF ALLYL CARBAMATES

Authors
DESSOLIN M GUILLEREZ MG THIERIET N GUIBE F LOFFET A
Citation
M. Dessolin et al., NEW ALLYL GROUP ACCEPTERS FOR PALLADIUM-CATALYZED REMOVAL OF ALLYLIC PROTECTIONS AND TRANSACYLATION OF ALLYL CARBAMATES, Tetrahedron letters, 36(32), 1995, pp. 5741-5744
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
32
Year of publication
1995
Pages
5741 - 5744
Database
ISI
SICI code
0040-4039(1995)36:32<5741:NAGAFP>2.0.ZU;2-P
Abstract
Allyl carboxylates. carbamates and phenoxides may be cleaved or transa cylated in the presence of palladium catalyst and either phenyltrihydr osilane or N-methyl-N-(trimethylsilyl)trifluoroacetamide. These reacti ons are totally compatible with the presence of Boc and, as far as phe nyltrihydrosilane is concerned, Fmoc protections.