HIGH-RESOLUTION FOURIER-TRANSFORM SPECTRA OF ASH3 - TRANSITIONS TO THE INTERACTING SUBLEVELS OF THE UPSILON-(4)=2 STATE

Authors
ULENIKOV ON MALIKOVA AB WINNEWISSER BP WINNEWISSER M
Citation
On. Ulenikov et al., HIGH-RESOLUTION FOURIER-TRANSFORM SPECTRA OF ASH3 - TRANSITIONS TO THE INTERACTING SUBLEVELS OF THE UPSILON-(4)=2 STATE, Journal of molecular spectroscopy, 172(2), 1995, pp. 330-343
Citations number
9
Categorie Soggetti
Spectroscopy,"Physics, Atomic, Molecular & Chemical
Journal title
Journal of molecular spectroscopy → ACNP
ISSN journal
00222852
Volume
172
Issue
2
Year of publication
1995
Pages
330 - 343
Database
ISI
SICI code
0022-2852(1995)172:2<330:HFSOA->2.0.ZU;2-U
Abstract
The high-resolution Fourier transform spectrum of the 2v(4) absorption band of the AsH3 molecule is analyzed. About 900 transitions (about 5 5% of them ''forbidden'') are assigned to the two components of the 2v (4) band. A set of parameters, including rotational and centrifugal di stortion constants and splitting and resonance parameters, is obtained which reproduces the initial experimental data within an rms deviatio n of 0.006 cm(-1). (C) 1995 Academic Press, Inc.