EFFECT OF ULTRAVIOLET-LIGHT ON A RADIATION-CURED OLIGOMERIC COMPOSITION

Citation
Va. Khoromskaya et al., EFFECT OF ULTRAVIOLET-LIGHT ON A RADIATION-CURED OLIGOMERIC COMPOSITION, High energy chemistry, 29(4), 1995, pp. 265-269
Citations number
8
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
00181439
Volume
29
Issue
4
Year of publication
1995
Pages
265 - 269
Database
ISI
SICI code
0018-1439(1995)29:4<265:EOUOAR>2.0.ZU;2-A
Abstract
The processes occurring in oligomeric systems under conditions of poly merization and accelerated aging induced by UV light were investigated using the method of IR spectroscopy. It was shown that photochemical degradation occurs primarily upon UV-light irradiation of cured epoxy acrylates at the ester groups and results in the formation of peroxyac ids. The principal possibility of introducing the stabilizer into the oligomeric composition at the radiation-curing stage was shown. The in troduction of benzon OA as a stabilizer is shown to reduce the rate of photodegradation.