Jk. Zachariah et al., POSTCRYSTALLIZATION DISTURBANCE IN THE NEODYMIUM AND LEAD-ISOTOPE SYSTEMS OF METABASALTS FROM THE RAMAGIRI SCHIST BELT, SOUTHERN INDIA, Geochimica et cosmochimica acta, 59(15), 1995, pp. 3189-3203
Archean metabasaltic rocks from three separate blocks that constitute
the north-south trending Ramagiri schist belt of the Eastern Dharwar C
raton have large variations in epsilon(Nd)(2750). Even samples of the
same rock type from one outcrop that are less than 50 cm apart from ea
ch other show a range of up to 5.5 epsilon(Nd)(2750) units. The trends
of the fields defined by the three suites in f(Sm/Nd) VS. epsilon(Nd)
(2750) space intersect at f(Sm/Nd) = +0.1 to +0.2 and epsilon(Nd)(2750
) = -8 to -12, suggesting that these racks have lost LREEs and have in
teracted with and exchanged at least Nd with a common extraneous phase
. The isotopic composition of this phase suggest derivation of its neo
dymium from sources which had a long-term history of LREE enrichment.
This phase may have derived its isotopic composition from older contin
ental crust. One of the unaltered dikes cutting the three blocks in th
e belt and the surrounding gneisses gives a Sm-147/Nd-144-Nd-143/Nd-14
4 age of 2454 +/- 100 Ma, a minimum for the time of block assembly and
alteration of REEs including Nd. While a set of samples from the cent
ral block lie along an isochron with a Pb-Pb age of 2746 +/- 64 Ma, th
e samples from the eastern and western blocks show large uncorrelated
variations in Pb-207/Pb-204 with Pb-206/Pb-204. Residues after acid le
aching of sample powders have lead isotope ratios that are distinct fo
r samples from each of the block, and are compatible with their deriva
tion from Archean mantle. The lead isotope composition of the acid lea
ches suggest disturbance of the metabasalts by an isotopically extrane
ous phase that had variable and high Pb-207/Pb-204 and Pb-208/Pb-204 r
atios for a given Pb-206/Pb-204, relative to expected Archean mantle v
alues. Both lead and neodymium isotope disturbances are best explained
as a result of alteration of these rocks by an extraneous phase which
had derived its isotopic composition from ca. 3.5 Ga continental crus
t.