Migration of paramagnetic probes from rigid PVC within 24 h at 50 degr
ees C depends on the simulant to a considerable extent. With a strongl
y swelling simulant like tert.butyl acetate, the rare of diffusion is
governed by the rate of penetration of the medium into the polymeric n
etwork. Isooctane has a very weak interaction with rigid PVC. With a m
ixture of tert.butyl acetate and isooctane it is possible to adjust th
e aggressivity of the medium and to tailor an alternative simulant tha
t interacts with the polymer in the same fashion as the EU's official
fatty food simulants. Particular responses of polar probes underline t
he importance of the interaction between simulant and additives in the
choice of alternative fatty food simulants for rigid PVC.