R. Bilbao et al., EXPERIMENTAL-STUDY AND MODELING OF THE BURNOUT ZONE IN THE NATURAL-GAS REBURNING PROCESS, Chemical Engineering Science, 50(16), 1995, pp. 2579-2587
The reburning process with natural gas is an effective technique which
can be applied in existing coal combustors in order to reduce the NOx
emissions. The importance of the burnout zone in this process is grea
t, because significant amounts of CO, unburned fuel and reactive nitro
gen can reach this zone. The influence of the temperature and the air
excess introduced in the burnout zone on the concentration of the nitr
ogenous species has been studied. Experimental results have been deter
mined of the concentrations of NO, HCN and NH3 in the exit gas for tem
peratures ranging between 900 and 1100 degrees C and air excesses betw
een 5 and 15%. An empirical correlation which fits the output NO conce
ntration has been obtained. A simplified model has been developed to p
redict the output concentrations of the most interesting nitrogenous s
pecies.