Porous silica is a unique matrix material for chemical sensors. In thi
s paper, porous silica is prepared via the sol-gel technique. The poro
sity, pore size, pore shape and pore-size distribution can be controll
ed by catalysts and preparation conditions. A porosity as high as 60-7
0% can be reached. The pore size can be controlled in the range 2-100
nm. A single narrow peak and double separate peak distributions can be
achieved by controlling the pH values. The pore shape can be controll
ed from narrow-necked and large-abdomened shapes to fine cylindrical p
ores. Applications of porous silica for chemical sensors are also disc
ussed in this paper.