Xd. Wang et al., TRANSITION BETWEEN NECK-CONTROLLED AND GRAIN-BOUNDARY-CONTROLLED SENSITIVITY OF METAL-OXIDE GAS SENSORS, Sensors and actuators. B, Chemical, 25(1-3), 1995, pp. 454-457
This paper studies the principles of gas-modulated grain-size effects
on the electrical conductivity and gas sensitivity of metal-oxide gas
sensors. A model that combines both the grain-boundary and neck mechan
isms is formulated based on the theories of thermionic emission and ju
nction modulation. The gas sensitivity is quantitatively discussed as
a function of grain size and chemisorbed gas concentration.