H. Kobayashi et al., ROLE AND MECHANISM OF THE FORMATION OF HYDROGEN-INDUCED INTERFACE STATES FOR PLATINUM SILICON-OXIDE SILICON MOS TUNNELING DIODES, Sensors and actuators. B, Chemical, 25(1-3), 1995, pp. 815-818
The mechanism of hydrogen sensing by Pt/silicon oxide/Si MOS tunnellin
g diodes has been investigated by measurements of current-voltage (I-V
) and conductance-voltage (G-V) curves and their time dependence after
the introduction of hydrogen. Interface states are formed by the reac
tion of the silicon oxide/Si interface with protons. The time constant
for the formation of the interface states increases with the hydrogen
concentration, which is explained by the formation of a two-dimension
al aggregation of interface states. The current flowing via the interf
ace states is predominant at a forward-bias voltage of 0.5 V and becom
es less predominant in the higher bias region.