The effect of the oxygen content in tin oxide films on selectivity in
gas detection has been studied. The experimental results show that sen
sors with different Sn:O ratios exhibit different behaviour in respons
e to CO and ethanol. A theoretical explanation of this phenomenon is p
resented, which is based on the density of oxygen vacancies at the sur
face. Moreover, a simple parametric method using three sensors with di
fferent Sn:O ratios has been tested to distinguish between CO and etha
nol.