To study the defect structure of MgO-doped lithium niobate, single cry
stals of lithium niobates (LiNbO3, ''LN'') with varying MgO content we
re characterized by chemical analysis, lattice parameters, and density
measurements. An Mg-incorporation mechanism was assumed on the basis
of the chemical formulae derived from the data and in light of our rec
ently proposed defect model of nondoped LN. At first, Mg would replace
the Nb ion at the Li site and complete replacement would take place a
t 3% MgO doping keeping the molar ratio Li/Nb = 0.94. This corresponds
to the formula [Li(0.94)Mg(0.03)square(0.03)][Nb-1.0]O-3. Further Mg
ions are incorporated into the Li site, replacing Li ions, with accomp
anying vacancy creation, down to Li/Nb = 0.84, which corresponds to th
e Nb-rich side limit of the LN solid solution range. The number of vac
ancies would reach a maximum at this composition and the formula would
be [Li(0.84)Mg(0.08)square(0.08)][Nb-1.0]O-3. Beyond this point, Mg i
ons enter the Nb and Li sites simultaneously, maintaining the Li/Nb ra
tio, leading to a decrease in vacancies. Two thresholds in the change
of composition and properties reported so far in the literature can be
interpreted by this model. Improved optical damage resistance due to
MgO-doping was attributed to the increase in vacancies, and not by its
decrease as was generally supposed. (C) 1995 Academic Press, Inc.