The effect of heating rate on the properties of ferroelectric lead mag
nesium niobate ceramics during calcining and sintering processes was r
eported in this investigation. Perovskite phase content, density, micr
ostructure, and the dielectric properties of PMN ceramics with the hea
ting rate from 2 degrees C/min to 30 degrees C/min were studied. Perov
skite phase content was affected by heating rate, especially on the su
rface exposed to air. A slow heating rate caused more evaporation of P
bO and resulted in porous ceramics with small grains. Increasing PMN c
ontent, density, and grain size with increasing heating rate made the
dielectric constant increase.