SYMMETRICAL OR UNSYMMETRIC CLEAVAGE OF THE BRIDGING SYSTEM IN [M(2)(MU-C6F5)(2)(C6F5)(4)](2-)(M(2)=PT-2, PD-2 OR PTPD) WITH 2,2'-BIPYRIDINEOR 1,10-PHENANTHROLINE - MOLECULAR-STRUCTURE OF [PPN](2)[(C6F5)(3)PT(MU-BPY)PT(C6F3)(3)] AND [NBU(4)][PT(C6F5)(3)(PHEN)]

Authors
USON R FORNIES J TOMAS M MARTINEZ F CASAS JM FORTUNO C
Citation
R. Uson et al., SYMMETRICAL OR UNSYMMETRIC CLEAVAGE OF THE BRIDGING SYSTEM IN [M(2)(MU-C6F5)(2)(C6F5)(4)](2-)(M(2)=PT-2, PD-2 OR PTPD) WITH 2,2'-BIPYRIDINEOR 1,10-PHENANTHROLINE - MOLECULAR-STRUCTURE OF [PPN](2)[(C6F5)(3)PT(MU-BPY)PT(C6F3)(3)] AND [NBU(4)][PT(C6F5)(3)(PHEN)], Inorganica Chimica Acta, 235(1-2), 1995, pp. 51-60
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
235
Issue
1-2
Year of publication
1995
Pages
51 - 60
Database
ISI
SICI code
0020-1693(1995)235:1-2<51:SOUCOT>2.0.ZU;2-D
Abstract
Binuclear M(2) (M = Pt, Pd) complexes with bridging N-N (N-N = bpy) [N Bu(4)](2)[M(2)(mu-N-N)(C6F5)(6)], mononuclear Pt complexes with monode ntate bpy or phen [NBu(4)][Pt(C6F5)(3)(N-N)] or neutral mononuclear Pt complexes with chelating phen [Pt(C6F5)(2)(N-N)] or Pd complexes with bpy or phen [Pd(C6F5)(2)(N-N)] can be prepared starting from [NBu(4)] (2)[M(2)(mu-C6F5)(2)(C6F5)(4)] by adequate choice of solvents and reac tions conditions. The crystal structures of [PPN](2)[Pt-2(mu-bpy)(C6F5 )(6)] and [NBu(4)][Pt(C6F5)(3)(phen)] have been established by X-ray c rystallography.