FERROMAGNETIC INTERMOLECULAR COUPLING IN THE NITRONYL NITROXIDE RADICAL NYL)-4,4,5,5-TETRAMETHLIMIDAZOLINE-1-OXYL-3-OXIDE, NIT(SME)PH

Authors
CANESCHI A FERRARO F GATTESCHI D LELIRZIN A RENTSCHLER E
Citation
A. Caneschi et al., FERROMAGNETIC INTERMOLECULAR COUPLING IN THE NITRONYL NITROXIDE RADICAL NYL)-4,4,5,5-TETRAMETHLIMIDAZOLINE-1-OXYL-3-OXIDE, NIT(SME)PH, Inorganica Chimica Acta, 235(1-2), 1995, pp. 159-164
Citations number
37
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
235
Issue
1-2
Year of publication
1995
Pages
159 - 164
Database
ISI
SICI code
0020-1693(1995)235:1-2<159:FICITN>2.0.ZU;2-2
Abstract
The nitronyl nitroxide radical, yl)-4,4,5,5-tetramethylimidazoline-1-o xyl-3-oxide, hereafter denoted NIT(SMe)Ph, has been synthesized and th e crystal structure solved. The space group and lattice parameters are PZ(1)/a (2=4), with a = 9.437(2), b = 19.827(2), c = 8.516(2)Angstrom and beta = 113.66(1)degrees. The magnetic behavior shown by this comp ound is dominated by ferromagnetic intermolecular coupling, as shown b y magnetic measurements and single crystal EPR spectra.