ALPHA-CARBONYL RADICALS FOR TOTAL SYNTHESIS OF NATURAL-PRODUCTS

Authors
SHA CK JEAN TS YAU NT HUANG SJ CHIOU RT YOUNG JF LIH SH TSENG WH
Citation
Ck. Sha et al., ALPHA-CARBONYL RADICALS FOR TOTAL SYNTHESIS OF NATURAL-PRODUCTS, Journal of the Chinese Chemical Society, 42(4), 1995, pp. 637-640
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Journal of the Chinese Chemical Society → ACNP
ISSN journal
00094536
Volume
42
Issue
4
Year of publication
1995
Pages
637 - 640
Database
ISI
SICI code
0009-4536(1995)42:4<637:ARFTSO>2.0.ZU;2-S
Abstract
Intramolecular cyclization of alpha-carbonyl radicals to the trimethyl silylacetylenic side chain gives bicyclic vinylsilane ketones and enon es. Application of this cyclization to total synthesis of (+/-)-modhep hene is described.