S. Berghmans et al., PHASE-BEHAVIOR AND STRUCTURE FORMATION IN SOLUTIONS OF POLY(2,6-DIMETHYL-1,4-PHENYLENE ETHER), Polymer, 36(16), 1995, pp. 3085-3091
The phase behaviour and the structure formation of solutions of poly(2
,6-dimethyl-1,4-phenylene ether) (PPE) in cyclohexanol and decalin hav
e been studied. Interesting structures were formed and the morphologie
s depended on the rate at which the solutions were cooled. This was ca
used by the competition between melting-crystallization, vitrification
and phase separation. Differential scanning electron microscopy (SEM)
was used to study the different morphologies. Porous materials can be
used as membranes. Hollow porous PPE fibres were spun.