THE STANDARD MOLAR ENTHALPIES OF FORMATION OF RARE-EARTH TRIHALIDES .2. CECL3(S) AND LACL3(S)

Authors
CORDFUNKE EHP BOOIJ AS
Citation
Ehp. Cordfunke et As. Booij, THE STANDARD MOLAR ENTHALPIES OF FORMATION OF RARE-EARTH TRIHALIDES .2. CECL3(S) AND LACL3(S), Journal of Chemical Thermodynamics, 27(8), 1995, pp. 897-900
Citations number
17
Categorie Soggetti
Chemistry Physical
Journal title
Journal of Chemical Thermodynamics → ACNP
ISSN journal
00219614
Volume
27
Issue
8
Year of publication
1995
Pages
897 - 900
Database
ISI
SICI code
0021-9614(1995)27:8<897:TSMEOF>2.0.ZU;2-T
Abstract
The standard molar enthalpies of solution of CeCl3(s) in HCl(aq) of co ncentration 0.234 mol . dm(-3), and LaCl3(s) in HCl(aq) of concentrati on 1.006 mol . dm(-3) have been measured. From these values the standa rd molar enthalpies of formation have been derived: Delta(f)H(m)(o)(Ce Cl3,s,298.15 K) = -(1060.5 +/- 0.5) kJ . mol(-1) and Delta(f)H(m)(o)(L aCl3,s,298.15 K) = - (1072.2 +/- 1.4) kJ . mol(-1). These results are compared with previous values from the literature. (C) 1995 Academic P ress Limited.