ZINC-PROMOTED BARBIER-TYPE REACTION OF PROPARGYL BROMIDE WITH ALDEHYDES IN AQUEOUS-MEDIA

Authors
YAVARI I RIAZIKERMANI F
Citation
I. Yavari et F. Riazikermani, ZINC-PROMOTED BARBIER-TYPE REACTION OF PROPARGYL BROMIDE WITH ALDEHYDES IN AQUEOUS-MEDIA, Synthetic communications, 25(19), 1995, pp. 2923-2928
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
25
Issue
19
Year of publication
1995
Pages
2923 - 2928
Database
ISI
SICI code
0039-7911(1995)25:19<2923:ZBROPB>2.0.ZU;2-T
Abstract
In the presence of metallic zinc, propargyl bromide is found to react with aldehydes at room temperature in tetrahydrofurane-saturated aqueo us ammonium chloride (5:2) to afford the corresponding homopropargylic alcohols in moderate to high yields together with small amounts of al pha-allenic alcohols.