ALKYLATION AND HYDROLYSIS OF PHENYLACETONITRILES UNDER MICROWAVE IRRADIATION

Citation
D. Barbry et al., ALKYLATION AND HYDROLYSIS OF PHENYLACETONITRILES UNDER MICROWAVE IRRADIATION, Synthetic communications, 25(19), 1995, pp. 3007-3013
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00397911
Volume
25
Issue
19
Year of publication
1995
Pages
3007 - 3013
Database
ISI
SICI code
0039-7911(1995)25:19<3007:AAHOPU>2.0.ZU;2-I
Abstract
Alkylation of phenylacetonitriles is performed by solid-liquid phase t ransfer catalysis in 1-3 minutes under microwave irradiation (one hour with a two-phase system). These nitriles can be quickly hydrolysed in a microwave oven to yield the corresponding amides or acids according to the reaction time.