SYNTHESIS OF OPTICALLY PURE, DIFFERENTIALLY PROTECTED 1,4-MANNOSYL-D-MYO-INOSITOL AND 1,6-MANNOSYL-D-MYO-INOSITOL DERIVATIVES FROM 7-OXABICYCLO[2.2.1]HEPTAN-2-ONE

Authors
ARJONA O DEDIOS A MONTERO C PLUMET J
Citation
O. Arjona et al., SYNTHESIS OF OPTICALLY PURE, DIFFERENTIALLY PROTECTED 1,4-MANNOSYL-D-MYO-INOSITOL AND 1,6-MANNOSYL-D-MYO-INOSITOL DERIVATIVES FROM 7-OXABICYCLO[2.2.1]HEPTAN-2-ONE, Tetrahedron, 51(33), 1995, pp. 9191-9200
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
51
Issue
33
Year of publication
1995
Pages
9191 - 9200
Database
ISI
SICI code
0040-4020(1995)51:33<9191:SOOPDP>2.0.ZU;2-P
Abstract
Efficient procedures to prepare 4-O-mannosyl conduritol B derivatives from mannosyl oxanorbornanes are described. The osmium-catalyzed cis-d ihydroxylation of the corresponding 1-O-acetates displays high pi-faci al selectivity syn to the acetate functionality to produce 1,4- and 1, 6-mannosyl-D-myo-inositol derivatives.