UNUSUAL REACTIVITY OF TRITYLCYCLOPENTADIENYLMETAL DERIVATIVES - MOLECULAR-STRUCTURE OF PH(3)CC(5)H(4)SNME(3) AND PH(3)CC(5)H(4)TICL(3)

Authors
RUFANOV KA CHURAKOV AV KAZENNOVA NB BRUSOVA GP LEMENOVSKII DA KUZMINA LG
Citation
Ka. Rufanov et al., UNUSUAL REACTIVITY OF TRITYLCYCLOPENTADIENYLMETAL DERIVATIVES - MOLECULAR-STRUCTURE OF PH(3)CC(5)H(4)SNME(3) AND PH(3)CC(5)H(4)TICL(3), Journal of organometallic chemistry, 498(1), 1995, pp. 37-39
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
498
Issue
1
Year of publication
1995
Pages
37 - 39
Database
ISI
SICI code
0022-328X(1995)498:1<37:UROTD->2.0.ZU;2-7
Abstract
The preparative synthetic routes to tritylcyclopentadienyl metal deriv atives of sodium, tin and titanium have been studied. Molecular struct ures of Ph(3)CC(5)H(4)SnMe(3) (3) and Ph(3)CC(5)H(4)TiCl(3) (4) have b een defined. The Cl-Ph agostic interaction in the structure of 4 provi des an unprecedented low reactivity of 4 to nucleophiles of different natures.