MOLECULAR-DYNAMICS OF STERICALLY HINDERED DIHALODIARYLTELLURANES AND DIACYLOXYDIARYLTELLURANES

Authors
TAKAGUCHI Y FUJIHARA H FURUKAWA N
Citation
Y. Takaguchi et al., MOLECULAR-DYNAMICS OF STERICALLY HINDERED DIHALODIARYLTELLURANES AND DIACYLOXYDIARYLTELLURANES, Journal of organometallic chemistry, 498(1), 1995, pp. 49-52
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
498
Issue
1
Year of publication
1995
Pages
49 - 52
Database
ISI
SICI code
0022-328X(1995)498:1<49:MOSHDA>2.0.ZU;2-I
Abstract
Dihalo- and diacyloxydi(2,6-dimethylphenyl)telluranes [10-Te-C2X2; X = halogen and RCO(2)] were prepared and variable-temperature H-1 NMR st udies revealed that these telluranes were composed of the sterically c ongested rotamers. The first examples of the activation parameters for rotation of the Te-C bonds were obtained in D NMR experiments.