ASYMMETRIC MICHAEL REACTION - DERACEMIZATION OF ENOLATE BY CHIRAL CROWN-ETHER

Authors
TOKE L FENICHEL L ALBERT M
Citation
L. Toke et al., ASYMMETRIC MICHAEL REACTION - DERACEMIZATION OF ENOLATE BY CHIRAL CROWN-ETHER, Tetrahedron letters, 36(33), 1995, pp. 5951-5954
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
33
Year of publication
1995
Pages
5951 - 5954
Database
ISI
SICI code
0040-4039(1995)36:33<5951:AMR-DO>2.0.ZU;2-L
Abstract
Crown ethers anellated to sugar units have been used to catalyse the e nantioselective carbon-carbon bond forming reaction of methyl phenylac etate with methyl acrylate. A novel CH-acid deracemization has also be en discovered in this study.