STERICALLY HINDERED ALUMINUM-MAGNESIUM BRIDGED COMPLEX - C-I)(2)]MG-2-[O-2,6-((C4H9)-C-T)(2)-4-MEC(6)H(2)])

Authors
CHANG CC HER TY LI MD WILLIAMSON R LEE GH PENG SM WANG Y
Citation
Cc. Chang et al., STERICALLY HINDERED ALUMINUM-MAGNESIUM BRIDGED COMPLEX - C-I)(2)]MG-2-[O-2,6-((C4H9)-C-T)(2)-4-MEC(6)H(2)]), Inorganic chemistry, 34(17), 1995, pp. 4296-4298
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
34
Issue
17
Year of publication
1995
Pages
4296 - 4298
Database
ISI
SICI code
0020-1669(1995)34:17<4296:SHABC->2.0.ZU;2-J
Abstract
The monomeric aluminum-magnesium bridged complex Me(2)Al[mu-N(Pr-i)(2) ]Mg-2(BHT), (BHT = 2,6-di-tert-butyl-4-methylphenoxide) with a three-c oordinate magnesium atom was prepared. Crystal data: space group P2(1) /n; a = 13.807(5), b = 15.636(4), and c = 14.905(3) Angstrom, beta = 9 5.03(3)degrees, V = 3205(2) Angstrom(3); D-calc = 1.038 g/cm(3), Z = 4 , and R = 0.056. Fenske-Hall molecular orbital calculations are used t o explain the bonding situation.