The replacement of hydrogen with its isotope deuterium, in collisions
with multiply charged ions, is shown to lead to a suppression of total
charge transfer cross sections at collision energies much higher than
previously thought. We demonstrate, using a fully quantal calculation
of electron capture in collisions of N4+(2s) with H(1s) and D(1s), th
at this isotope effect is significant for capture into the N3+(3d) sta
tes at collision energies approaching 10 eV/amu. Estimates of the magn
itude of the effect, using the semiclassical Landau-Zener-Stueckelberg
model, are made for several multiply charged systems.