Electrical current fluctuations through tunnel junctions are studied w
ith a scanning-tunneling microscope. For single-tunnel junctions class
ical Poisson shot noise is observed, indicative for uncorrelated tunne
ling of electrons. For double-barrier tunnel junctions, formed by a na
noparticle between tip and surface, the shot noise is observed to be s
uppressed below the Poisson value. For strongly asymmetric junctions,
where a Coulomb staircase is observed in the current-voltage character
istic, the shot-noise suppression is periodic in the applied voltage.
This originates from correlations in the transfer of electrons imposed
by single-electron charging effects.