STEREOSPECIFIC SYNTHESIS OF NOVEL DIVINYL ETHER OXYLIPINS BY THE ENZYME FROM GARLIC BULBS

Authors
GRECHKIN AN HAMBERG M
Citation
An. Grechkin et M. Hamberg, STEREOSPECIFIC SYNTHESIS OF NOVEL DIVINYL ETHER OXYLIPINS BY THE ENZYME FROM GARLIC BULBS, Bioorganiceskaa himia, 22(12), 1996, pp. 944-945
Citations number
3
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Bioorganiceskaa himia → ACNP
ISSN journal
01323423
Volume
22
Issue
12
Year of publication
1996
Pages
944 - 945
Database
ISI
SICI code
0132-3423(1996)22:12<944:SSONDE>2.0.ZU;2-H
Abstract
Oxidation of (9Z,11E,13R,S)-13-hydroperoxy-9,11-octadecadienoic acid b y the synthase of divinyl ethers from garlic bulbs (Allium sativum L.) was studied. The enzyme was found to be partially stereospecific, pre ferentially using the (13S)-epimer of hydroperoxide.