ELECTROCHEMICAL SYNTHESIS IN 2-PHASE SYSTEM - REDUCTION OF 4-METHYL-1,1,1-TRICHLORO-4-PENTEN-2-OL

Authors
SMIRNOV YD TOMILOV AP
Citation
Yd. Smirnov et Ap. Tomilov, ELECTROCHEMICAL SYNTHESIS IN 2-PHASE SYSTEM - REDUCTION OF 4-METHYL-1,1,1-TRICHLORO-4-PENTEN-2-OL, Russian journal of electrochemistry, 31(7), 1995, pp. 655-659
Citations number
11
Categorie Soggetti
Electrochemistry
Journal title
Russian journal of electrochemistry → ACNP
ISSN journal
10231935
Volume
31
Issue
7
Year of publication
1995
Pages
655 - 659
Database
ISI
SICI code
1023-1935(1995)31:7<655:ESI2S->2.0.ZU;2-7
Abstract
The possibility of synthesis of 1,1-dichloro-4-methyl-1,4-pentadiene b y electrochemical reduction of 4-methyl-1,1,1-trichloro-4-penten-2-ol is shown. Influence of cosolvent nature, supporting electrolyte, and c athode material on the reduction process is studied. The maximum yield of the final product (74 - 82% by substance and 54 - 66% by current) is obtained in the system isopropanol-p-toluenesulfonic acid on lead c athode.