A method is proposed in which diode-array UV-visible spectroscopy and
multivariate data analysis are applied to determine nitrate in municip
al waste water. No filtering of the samples is required and no reagent
s are added. The working range for the nitrate determination is 0.5-13
.7 mg/l (0.008-0.22 mM). The relative standard deviation was found to
be 3.4%. Other constituents, notably total phosphorus, total nitrogen,
ammonium nitrogen and iron can be determined simultaneously with the
same method. The developed method can also be used to classify samples
. The described method concept is well suited for in-line monitoring.