THE X-RAY CRYSTAL-STRUCTURE OF BIS(DICYCLOHEXYLDITHTOPHOSPHATO)CADMIUM(II)

Authors
CASAS JS CASTINEIRAS A GARCIATASENDE MS SANCHEZ A SORDO J VAZQUEZLOPEZ EM
Citation
Js. Casas et al., THE X-RAY CRYSTAL-STRUCTURE OF BIS(DICYCLOHEXYLDITHTOPHOSPHATO)CADMIUM(II), Polyhedron, 14(15-16), 1995, pp. 2055-2058
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
14
Issue
15-16
Year of publication
1995
Pages
2055 - 2058
Database
ISI
SICI code
0277-5387(1995)14:15-16<2055:TXCOB>2.0.ZU;2-W
Abstract
The compound bis(dicyclohexyldithiophosphato)cadmium(II), [Cd {S2P (OC y)(2)}(2)], has been obtained by reacting cadmium(II) perchlorate with the sodium salt of dicyclohexyldithiophosphoric acid in ethanol. Its structure was solved by X-ray diffraction. The structure consists of d imers in which each metal centre is coordinated by a chelating ligand and two bridging ligands, giving a coordination number of 4. The two b ridging ligands and the two cadmium atoms form an eight-membered ring with a twisted chair conformation.