ROTATIONALLY RESOLVED PHOTOELECTRON-SPECTROSCOPY OF THE [A(1)DELTA]3D-PI(2)PHI RYDBERG STATE OF THE SH RADICAL

Authors
MILAN JB BUMA WJ DELANGE CA WANG KH MCKOY V
Citation
Jb. Milan et al., ROTATIONALLY RESOLVED PHOTOELECTRON-SPECTROSCOPY OF THE [A(1)DELTA]3D-PI(2)PHI RYDBERG STATE OF THE SH RADICAL, The Journal of chemical physics, 103(8), 1995, pp. 3262-3264
Citations number
14
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
The Journal of chemical physics → ACNP
ISSN journal
00219606
Volume
103
Issue
8
Year of publication
1995
Pages
3262 - 3264
Database
ISI
SICI code
0021-9606(1995)103:8<3262:RRPOT[>2.0.ZU;2-Y
Abstract
Results of calculated and measured photoelectron spectra via the [a (1 ) Delta]3d pi (2) Phi state of SH are reported. These spectra show a s trong asymmetry away from classical expectations and only transitions up to Delta N=+/-2 are observed, in contrast to Delta N=+/-4 expected for photoionization of a 3d pi orbital. Agreement between the calculat ed and measured spectra is excellent. (C) 1995 American Institute of P hysics.