Jb. Milan et al., ROTATIONALLY RESOLVED PHOTOELECTRON-SPECTROSCOPY OF THE [A(1)DELTA]3D-PI(2)PHI RYDBERG STATE OF THE SH RADICAL, The Journal of chemical physics, 103(8), 1995, pp. 3262-3264
Results of calculated and measured photoelectron spectra via the [a (1
) Delta]3d pi (2) Phi state of SH are reported. These spectra show a s
trong asymmetry away from classical expectations and only transitions
up to Delta N=+/-2 are observed, in contrast to Delta N=+/-4 expected
for photoionization of a 3d pi orbital. Agreement between the calculat
ed and measured spectra is excellent. (C) 1995 American Institute of P
hysics.