SYNTHESIS, X-RAY STRUCTURE AND COORDINATION TO MN(CO)(3)(BIPY)(-2)(6)AND N3P3(OC5H4N-4)(6)() OF THE CYCLOTRIPHOSPHAZENES N3P3(OC5H4N)

Authors
CARRIEDO GA ELIPE PG ALONSO FJG FERNANDEZCATUXO L DIAZ MR GRANDA SG
Citation
Ga. Carriedo et al., SYNTHESIS, X-RAY STRUCTURE AND COORDINATION TO MN(CO)(3)(BIPY)(-2)(6)AND N3P3(OC5H4N-4)(6)() OF THE CYCLOTRIPHOSPHAZENES N3P3(OC5H4N), Journal of organometallic chemistry, 498(2), 1995, pp. 207-212
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
498
Issue
2
Year of publication
1995
Pages
207 - 212
Database
ISI
SICI code
0022-328X(1995)498:2<207:SXSACT>2.0.ZU;2-9
Abstract
The hexachlorocyclotriphosphazene [N3P3Cl6] reacts with 2-hydroxypyrid ine (HOC5H4N-2) and 4-hydroxypyridine (HOC5H4N-4) in acetone in the pr esence of K2CO3, to give the hexasubstituted products N3P3(OC5H4N-2)(6 ) (1) and N3P3(OC5H4N-4)(6) (2). The structure of both compounds has b een determined by X-ray diffraction. The hexafunctionalized cyclotriph osphazene N3P3(OC5H4N-4)(6) (2) is a better ligand than 1 and reacts w ith fac-[Mn(OClO3)(CO)(3)(bipy)] in CH2Cl2 to give the hexacationic co mplex [N3P3{(OC5H4N)Mn(CO)(3)(bipy)}(6)](ClO4)(6) (3).