A NEW LANGBEINITE - DIPOTASSIUM DIMANGANESE TETRAFLUOROBERYLLATE

Citation
A. Guelylah et al., A NEW LANGBEINITE - DIPOTASSIUM DIMANGANESE TETRAFLUOROBERYLLATE, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 2951-2954
Citations number
16
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
12
Pages
2951 - 2954
Database
ISI
SICI code
0108-2701(1996)52:<2951:ANL-DD>2.0.ZU;2-T
Abstract
The structure of the cubic phase of a new langbeinite, K2Mn2(BeF4)(3), has been determined at 293 K from Xray diffraction data. Differential scanning calorimetry measurements in the temperature range 100-300 K indicated a new phase transition at 213 K, which has been confirmed by precession X-ray diffractograms, revealing a new type of structure di fferent to those generally expected for the low-temperature phases of langbeinites.