RUTHENIUM(II) COMPLEX CONTAINING A NEW HYBRID BIDENTATE PHOSPHINE-THIOETHER LIGAND - )RUCL-(ME(2)PCH(2)CH(2)SME)][BPH(4)].0.5CH(2)CL(2)

Authors
SUZUKI T TAGUCHI N KAZUO K
Citation
T. Suzuki et al., RUTHENIUM(II) COMPLEX CONTAINING A NEW HYBRID BIDENTATE PHOSPHINE-THIOETHER LIGAND - )RUCL-(ME(2)PCH(2)CH(2)SME)][BPH(4)].0.5CH(2)CL(2), Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 2982-2984
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
12
Pages
2982 - 2984
Database
ISI
SICI code
0108-2701(1996)52:<2982:RCCANH>2.0.ZU;2-Q
Abstract
In the title compound, lphosphino-P)-2-(methylthio-S)ethane]ruthenium( II) tetraphenylborate hemidichloromethane solvate, RuCl-(C10H14)(C5H13 PS)][B(C6H5)(4)].0.5CH(2)Cl(2), the hybrid Me(2)PCH(2)CH(2)SMe ligand is bidentate (kappa(2) P,S), forming a five-membered chelate ring. The complex cation has two chiral centres, i.e, on the Ru and S atoms, an d the relative configuration is R(Ru)S*(S).