RHODA-7-THIA-NIDO-UNDECABORANE(10)-DICHLOROMETHANE (2 1)/

Authors
ROSAIR GM WELCH AJ WELLER AS
Citation
Gm. Rosair et al., RHODA-7-THIA-NIDO-UNDECABORANE(10)-DICHLOROMETHANE (2 1)/, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 3020-3024
Citations number
10
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
12
Pages
3020 - 3024
Database
ISI
SICI code
0108-2701(1996)52:<3020:R(1>2.0.ZU;2-W
Abstract
The solid-state structure of the title compound, [Rh(B9H10S)(C26H24P2) ].0.5CH(2)Cl(2), has a nido cluster geometry but, apparently, only a c loso electron count. This anomaly is rationalized in terms of long ran ge ortho-phenyl agostic C-H...Rh interactions.