NEUTRAL SALT EFFECT IN THE POLYMERIZATION OF N-VINYLCARBAZOLE BY TRITYL CATION IN NITROBENZENE

Authors
GONZALEZ M RODRIGUEZ M LEON LM
Citation
M. Gonzalez et al., NEUTRAL SALT EFFECT IN THE POLYMERIZATION OF N-VINYLCARBAZOLE BY TRITYL CATION IN NITROBENZENE, Pure and applied chemistry, A32(10), 1995, pp. 1773-1780
Citations number
9
Categorie Soggetti
Polymer Sciences
Journal title
Pure and applied chemistry → ACNP
ISSN journal
00334545
Volume
A32
Issue
10
Year of publication
1995
Pages
1773 - 1780
Database
ISI
SICI code
0033-4545(1995)A32:10<1773:NSEITP>2.0.ZU;2-6
Abstract
The polymerization of N-vinylcarbazole in the presence of the PhCH(2)( CH3)(3)N+SbF6- salt has been studied at different temperatures (293 an d 308 K) in nitrobenzene. An increase in k(p) at high [salt]/[I](0) ra tios has been observed which can be explained by the strong interactio ns of the nitrobenzene solvent with the monomer and the propagating sp ecies.