N-(TERT-BUTOXYCARBONYL)-2-PHENYLGLYCINE

Authors
GONZALEZCAMENO AM BADIA D DOMINGUEZ E ARRIORTUA MI URTIAGA MK SOLANS X
Citation
Am. Gonzalezcameno et al., N-(TERT-BUTOXYCARBONYL)-2-PHENYLGLYCINE, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 3169-3171
Citations number
10
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
12
Pages
3169 - 3171
Database
ISI
SICI code
0108-2701(1996)52:<3169:N>2.0.ZU;2-C
Abstract
In solution at room temperature N-(tert-butoxy-carbonyl)-2-phenylglyci ne, C13H17NO4, shows the presence of two confomers, Z and E in the rat io 1:3, as a result of restricted rotation about the N-CO bond. In the solid state, however, only the Z isomer was observed [HN-N-C2-O4 173. 1(4)degrees] with the N-CO bond showing considerable double-bond chara cter [N-C2 1.357(3) Angstrom].