COMPARISON OF ESR-SPECTRA OF 2 CU(II) SALTS IN SOME AMIDE SOLUTIONS

Citation
B. Robers et M. Stockhausen, COMPARISON OF ESR-SPECTRA OF 2 CU(II) SALTS IN SOME AMIDE SOLUTIONS, Zeitschrift fur Naturforschung. A, A journal of physical sciences, 50(8), 1995, pp. 779-784
Citations number
23
Categorie Soggetti
Chemistry Physical",Physics
ISSN journal
09320784
Volume
50
Issue
8
Year of publication
1995
Pages
779 - 784
Database
ISI
SICI code
0932-0784(1995)50:8<779:COEO2C>2.0.ZU;2-7
Abstract
X-band ESR spectra of liquid solutions of Cu(II)nitrate and Cu(II)chlo ride in N-methylformamide and four N,N-disubstituted amides are report ed and discussed with respect to the occurrence of ion pairs or higher ionic aggregations. Nitrate solutions allow to distinguish two comple x types of moderate asymmetry at most. Chloride solutions indicate a s uccession of at least three complex types with strongly increasing asy mmetry.