Ms. Cheong et Hj. Kang, AN EFFECTIVE RHODIUM CATALYST SYSTEM ON THE SYNTHESIS OF ACETIC-ACID FROM METHYL FORMATE, The Korean journal of chemical engineering, 12(3), 1995, pp. 396-398
Rh/Lil/SnR(4) is an effective catalyst system for the conversion of me
thyl formate to acetic acid under carbon monoxide pressure. The effect
s of solvent and initial CO partial pressure on the turnover rate of t
he reaction were investigated. The possibility of replacing some of th
e iodide promoters by tin compounds has been probed.