The character of fireside ash deposits depend on the processes by whic
h deposits are formed and subsequent reactions within the deposit and
with furnace gases. The properties influencing furnace heat transfer,
absorptivity for radiative transfer and thermal conductivity for condu
ctive transfer are shown from many measurements to depend on this char
acter. Illustrative trends in these properties as deposits mature and
grow are presented together with their effect on furnace exit temperat
ure and efficiency. The reflective character of initial deposits from
particular coals is then considered with predictions and measurements
of the spectral character of such deposits, during the first three hou
rs of growth, using on-line FTIR spectroscopy.