PHASE-DIAGRAM OF NACL-ALCL3-SECL4 SYSTEM AND ELECTRICAL CONDUCTIVITIES OF THE MELTS

Authors
MURAKAMI Y SAWATA A YASHIMA Y
Citation
Y. Murakami et al., PHASE-DIAGRAM OF NACL-ALCL3-SECL4 SYSTEM AND ELECTRICAL CONDUCTIVITIES OF THE MELTS, Denki Kagaku Oyobi Kogyo Butsuri Kagaku, 63(8), 1995, pp. 733-736
Citations number
11
Categorie Soggetti
Electrochemistry
Journal title
Denki Kagaku Oyobi Kogyo Butsuri Kagaku → ACNP
ISSN journal
03669297
Volume
63
Issue
8
Year of publication
1995
Pages
733 - 736
Database
ISI
SICI code
0366-9297(1995)63:8<733:PONSAE>2.0.ZU;2-K
Abstract
NaCl-AlCl3-SeCl4 melts are attractive for a Na/SeCl4 battery, and the liquidus temperature of this system has been determined as a function of composition by differential thermal analysis. The ternary eutectic composition is (NaCl)(20)(AlCl3)(59) (SeCl4)(21) and its temperature i s 42 degrees(C). Phase relation of NaCl-AlCl3-SeCl4 system at 200 degr ees(C) was also determined. Electrical conductivities of quasibinary ( NaCl)(45) (AlCl3)(55)-SeCl4 melts tend to decrease with increasing con tent of SeCl4.