We have studied via in-beam gamma-ray spectroscopy Po-196 and Po-198,
which are the first neutron-deficient Po isotopes to exhibit a collect
ive low-lying structure. The ratios of yrast state energies and the E2
branching ratios of transitions from non-yrast to yrast states are in
dicative of a low-lying vibrational structure. The onset of collective
motion in these isotopes can be attributed to the opening of the neut
ron i(13/2) orbital at N approximate to 112 and the resulting large ov
erlap between the two valence protons in the h(9/2) orbital and the va
lence neutrons in the i(13/2) orbital.