Rc. Price et al., STRONTIUM ISOTOPIC AND TRACE-ELEMENT HETEROGENEITY IN THE PLAINS BASALTS OF THE NEWER VOLCANIC PROVINCE, VICTORIA, AUSTRALIA, Geochimica et cosmochimica acta, 61(1), 1997, pp. 171-192
The plains sub-province of the Newer Volcanics of Victoria Australia i
s a lava plain, ranging in age from 4.5 Ma to < 10 ka and covering an
area of 15000 km(2), punctuated by generally younger (< 10-300 ka) cin
der cones, lava shields, and maars. Analyses of over four hundred and
fifty lavas for major and trace element and strontium isotopic composi
tion show that the plains basalt suite is dominated by tholeiitic and
transitional basalts with alkaclic rock types and basaltic icelandites
being less common. There is a continuous transition from alkalic type
s through to quartz tholeiites and basaltic icelandites. SiO2 contents
are positively correlated with Sr-87/Sr-86 and negatively correlated
with K2O contents. Abundances of incompatible elements such as K, P, T
i, Sr, and Nb are linearly correlated. Trace element and isotopic patt
erns indicate that a component with a crustal geochemical signature (h
igh Sr-87/Sr-86, high K/Nb, and high Pb/Ce) was involved in the genera
tion and/or evolution of some basaltic icelandites. The possibility th
at the crustal geochemical signature reflects assimilation/crystal fr
actionation processes cannot be entirely precluded, but it is more lik
ely that isotopic and trace element variation for the more magnesian l
avas of the sub-province, including basaltic icelandites with relative
ly high magnesium numbers, reflects heterogeneity in the mantle source
s. Projected onto an east-west profile through the sub-province, the s
trontium isotopic data reveal a north-south boundary (the Mortlake Dis
continuity) separating eastern and western sectors with different mean
strontium isotopic ratios. The basalts of the eastern sector show a h
igher mean Sr-87/Sr-86 ratio (0.7047) and the ratios are more variable
(0.7037-0.7058) than is the case in the western sector (mean is 0.704
2 and all but one sample in the range 0.7037-0.7046). The Mortlake dis
continuity coincides with a major tectonic boundary separating the two
principal Palaeozoic mobile belts of southeastern Australia. It is pr
oposed that the tectonic boundary extends into the subcontinental lith
osphere and that the isotopic and geochemical differences observed in
the basalts of eastern vs. the western sectors arise because of differ
ences in the geochemistry of heterogeneous lithospheric mantle on eith
er side of this boundary. Strontium isotopic analyses in conjunction w
ith other geochemical information, geomorphological and petrographic o
bservations, and available geochronological information have also been
used to define isotopic domains in the sub-province ranging in size f
rom a few up to several hundred square kilometres. The isotopic domain
s define individual flows or groups of flows representing individual m
agma batches and it is postulated that the domains in part reflect sma
ll scale geochemical heterogeneity in the lithospheric mantle. Copyrig
ht (C) 1997 Elsevier Science Ltd