NOVEL ALKYLATION ANNULATION REACTION OF FISCHER CARBENE COMPLEXES

Authors
AMIN SR SAWANT SS PURANIK VG SARKAR A
Citation
Sr. Amin et al., NOVEL ALKYLATION ANNULATION REACTION OF FISCHER CARBENE COMPLEXES, Organometallics, 14(8), 1995, pp. 3617-3619
Citations number
41
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
14
Issue
8
Year of publication
1995
Pages
3617 - 3619
Database
ISI
SICI code
0276-7333(1995)14:8<3617:NAAROF>2.0.ZU;2-K
Abstract
Alkylation of aminocarbene complexes (CO)(5)M=C(CH3)(NHR) with dichlor omethane or dibromomethane under PTC conditions triggers an annulation . reaction, leading to novel cyclic products. This is the first exampl e of such reactivity of Fischer carbene complexes.