M. Godefroid et al., ACCURATE MULTICONFIGURATION HARTREE-FOCK CALCULATIONS OF OSCILLATOR-STRENGTHS IN LIGHT-ATOMS - THE BORON (B-II) LINE AT 1362 ANGSTROM, The Astrophysical journal, 450(1), 1995, pp. 473-476
A new method to deal with nonorthogonalities in transition calculation
s has been implemented and tested. Large-scale transition calculations
using the multiconfiguration Hartree-Fock (MCHF) method have been per
formed for the resonance line of B II at 1362 Angstrom. In these calcu
lations the orbital sets of the initial and final-state wavefunctions
have not been assumed to be equal but have been optimized independentl
y. The calculated weighted multiplet oscillator strength gf= 0.999 has
an estimated uncertainty of less than 0.5%. Together with the previou
sly calculated isotope shift and hyperfine structure (Jonsson, Johanss
on, and Froese Fischer 1994), all the important atomic parameters need
ed for a detailed modeling of the B II resonance line in high-resoluti
on astrophysical spectra are now available with high accuracy.