DEGRADATION KINETICS OF RESOL-MODIFIED EPOXY .1.

Citation
D. Srivastava et Gn. Mathur, DEGRADATION KINETICS OF RESOL-MODIFIED EPOXY .1., Journal of macromolecular science. Pure and applied chemistry, A34(1), 1997, pp. 59-66
Citations number
18
Categorie Soggetti
Polymer Sciences
ISSN journal
10601325
Volume
A34
Issue
1
Year of publication
1997
Pages
59 - 66
Database
ISI
SICI code
1060-1325(1997)A34:1<59:DKORE.>2.0.ZU;2-E
Abstract
Blends of resole with epoxy resin (General Purpose) having different w eight ratios (0/100, 25/75, 50/50, 75/25, and 100/0) based on physical mixing have been prepared. These blends were cured by adding polyamid e in a 60:40 ratio based on blend resins and polyamide. The degradatio n kinetics of these resins was studied by dynamic thermogravimetric an alysis in nitrogen atmosphere at a heating rate of 15 degrees C/min by using the Coats-Redfern equation. It is concluded that the degradatio n of each sample follows first-order (n = 1) degradation kinetics. Thi s is obtained on the basis of best fit analysis, and all the parameter s are confirmed by regression analysis. From the reaction order value, activation energy (E) and preexponential factor (Z) were calculated b y the slope and intercept of the plot between X and Y, respectively.