D. Srivastava et Gn. Mathur, DEGRADATION KINETICS OF RESOL-MODIFIED EPOXY .1., Journal of macromolecular science. Pure and applied chemistry, A34(1), 1997, pp. 59-66
Blends of resole with epoxy resin (General Purpose) having different w
eight ratios (0/100, 25/75, 50/50, 75/25, and 100/0) based on physical
mixing have been prepared. These blends were cured by adding polyamid
e in a 60:40 ratio based on blend resins and polyamide. The degradatio
n kinetics of these resins was studied by dynamic thermogravimetric an
alysis in nitrogen atmosphere at a heating rate of 15 degrees C/min by
using the Coats-Redfern equation. It is concluded that the degradatio
n of each sample follows first-order (n = 1) degradation kinetics. Thi
s is obtained on the basis of best fit analysis, and all the parameter
s are confirmed by regression analysis. From the reaction order value,
activation energy (E) and preexponential factor (Z) were calculated b
y the slope and intercept of the plot between X and Y, respectively.