3-CYCLOHEXYLOXY-2-HYDROXYPROPYL ACRYLATE-STYRENE COPOLYMERS - SYNTHESIS, CHARACTERIZATION, AND REACTIVITY RATIOS

Authors
COSKUN M ERTEN H OZDEMIR E AHMEDOV MA
Citation
M. Coskun et al., 3-CYCLOHEXYLOXY-2-HYDROXYPROPYL ACRYLATE-STYRENE COPOLYMERS - SYNTHESIS, CHARACTERIZATION, AND REACTIVITY RATIOS, Journal of macromolecular science. Pure and applied chemistry, A34(1), 1997, pp. 91-98
Citations number
11
Categorie Soggetti
Polymer Sciences
Journal title
Journal of macromolecular science. Pure and applied chemistry → ACNP
ISSN journal
10601325
Volume
A34
Issue
1
Year of publication
1997
Pages
91 - 98
Database
ISI
SICI code
1060-1325(1997)A34:1<91:3AC-S>2.0.ZU;2-J
Abstract
Copolymers of 3-cyclohexyloxy-2-hydroxypropyl acrylate (HHPA) with sty rene were prepared by free-radical-initiated solution polymerization i n 1,4-dioxane. H-1 and C-13 nuclear magnetic resonance techniques were used in the polymer characterization. Glass transition temperatures a s a function of HHPA in copolymer changed from 76 to 17 degrees C. The copolymer compositions were determined by elemental analysis and H-1- NMR spectra. Reactivity ratios were calculated as r(HHPA) = 0.37 +/- 0 .34 and r(styrene) = 1.10 +/- 0.47 from the Kelen-Tudos equation, and r(HHPA) = 0.31 +/- 0.08 and r(styrene) = 0.95 +/- 0.37 from the Finema n-Ross equation.