NOVEL INTRAMOLECULAR MICHAEL-TYPE REACTIONS BETWEEN VINYLDIPHENYLPHOSPHINE AND PENTAMETHYLCYCLOPENTADIENYL COORDINATED TO RHODIUM(III) - FORMATION AND X-RAY STRUCTURES OF HEPTADENTATE 10-ELECTRON DONOR LIGANDS

Authors
BARTHELROSA LP CATALANO VJ NELSON JH
Citation
Lp. Barthelrosa et al., NOVEL INTRAMOLECULAR MICHAEL-TYPE REACTIONS BETWEEN VINYLDIPHENYLPHOSPHINE AND PENTAMETHYLCYCLOPENTADIENYL COORDINATED TO RHODIUM(III) - FORMATION AND X-RAY STRUCTURES OF HEPTADENTATE 10-ELECTRON DONOR LIGANDS, Journal of the Chemical Society, Chemical Communications, (16), 1995, pp. 1629-1630
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
16
Year of publication
1995
Pages
1629 - 1630
Database
ISI
SICI code
0022-4936(1995):16<1629:NIMRBV>2.0.ZU;2-A
Abstract
The reaction between vinyldiphenylphosphine and [{(eta(5)-C(5)Me(5))Rh Cl2}(2)] proceeds via an intramolecular hydroalkyl addition to yield t he two isomeric products 1a and 2a.